Broadband Underwater Acoustic Sensing Using Pressure-Stable Relaxor Single-Crystal Hydrophones: A Review
Keywords:
Relaxor ferroelectric; piezoelectric single crystal; hydrophone; underwater acoustic sensing; PMN-PT; PIN-PMN-PT; deep-sea pressure; piezocomposite.Abstract
Relaxor-ferroelectric single crystals may be used to increase hydrophone sensitivity and a wide bandwidth, however, in response to loading conditions, pressure, temperature, bias and cyclic loading, the domain state in the single crystals vary. This survey covers pressure stable broadband receivers using PMN-PT, PIN-PMN-PT, PZN-PT, doping and polymer composites. There are thirty journal papers indexed in DOI from the years 2015 to August 2026 based on crystal chemistry and growth, domain engineering, composite connectivity, receiver architecture, packaging, and qualification evidence. The fabricated tank-tested composites bring finite-element concepts and transmitter-only demonstrations to a halt. The synthesis states that main challenge to be faced in synthesis is maintaining calibrated receiving sensitivity and low self-noise from combined pressure-temperature-bias histories. Practical validation protocol and a deployment evidence ladder are proposed.
References
[1] F. Tian, Y. Liu, R. Ma, F. Li, Z. Xu, and Y. Yang, "Properties of PMN-PT single crystal piezoelectric material and its application in underwater acoustic transducer," Appl. Acoust., vol. 175, Art. no. 107827, 2021, doi: 10.1016/j.apacoust.2020.107827.
[2] S. Pyo, J. Kim, H. Kim, and Y. Roh, "Development of vector hydrophone using thickness-shear mode piezoelectric single crystal accelerometer," Sens. Actuators A Phys., vol. 283, pp. 220-227, 2018, doi: 10.1016/j.sna.2018.09.066.
[3] Y. Cho, Y. Je, and W. B. Jeong, "A miniaturized acoustic vector sensor with PIN-PMN-PT single crystal cantilever beam accelerometers," Acta Acust., vol. 4, no. 5, Art. no. 17, 2020, doi: 10.1051/aacus/2020017.
[4] T. Roh, H. G. Yeo, C. Joh, Y. Roh, K. Kim, H. S. Seo, et al., "Fabrication and Underwater Testing of a Vector Hydrophone Comprising a Triaxial Piezoelectric Accelerometer and Spherical Hydrophone," Sensors, vol. 22, no. 24, Art. no. 9796, 2022, doi: 10.3390/s22249796.
[5] Y. Je, M. Sim, Y. Cho, S. G. Lee, and H. S. Seo, "Theoretical and Experimental Studies on Sensitivity and Bandwidth of Thickness-Mode Driving Hydrophone Utilizing A 2-2 Piezoelectric Single Crystal Composite," Sensors, vol. 23, no. 7, Art. no. 3445, 2023, doi: 10.3390/s23073445.
[6] Q. Shi, Z. He, H. Xu, C. Lin, and S. Zhang, "Performance of relaxor ferroelectric single crystal transducer under high hydrostatic pressure," Sens. Actuators A Phys., vol. 360, Art. no. 114523, 2023, doi: 10.1016/j.sna.2023.114523.
[7] H. G. Yeo, J. Choi, C. Jin, S. Pyo, Y. Roh, and H. Choi, "The Design and Optimization of a Compressive-Type Vector Sensor Utilizing a PMN-28PT Piezoelectric Single-Crystal," Sensors, vol. 19, no. 23, Art. no. 5155, 2019, doi: 10.3390/s19235155.
[8] X. Yin, W. Lu, C. Wang, and W. Cao, "Investigation of single-crystal face-plated 2-2 piezocomposites for deep-sea hydrophone applications," J. Acoust. Soc. Am., vol. 159, no. 3, pp. 1963-1972, 2026, doi: 10.1121/10.0042848.
[9] T. Wang, X. Zhao, H. Du, S. Xia, G. Li, H. Guo, et al., "Large-Area Piezoelectric Single Crystal Composites via 3-D-Printing-Assisted Dice-and-Insert Technology for Hydrophone Applications," IEEE Trans. Ultrason. Ferroelectr. Freq. Control, vol. 68, no. 10, pp. 3241-3248, 2021, doi: 10.1109/tuffc.2021.3085842.
[10] N. Jia, T. Wang, J. Duan, K. Qiang, S. Xia, H. Du, et al., "High-Performance Curved Piezoelectric Single-Crystal Composites via 3D-Printing-Assisted Dice and Insert Technology for Underwater Acoustic Transducer Applications," ACS Appl. Mater. Interfaces, vol. 14, no. 6, pp. 8137-8145, 2022, doi: 10.1021/acsami.1c21010.
[11] E. Sagaas Røed, M. Bring, M. Frijlink, A. Henriksen, F. Tichy, E. M. Åsjord, et al., "Underwater single crystal piezocomposite transducer with extended usable frequency band," Ultrasonics, vol. 125, Art. no. 106794, 2022, doi: 10.1016/j.ultras.2022.106794.
[12] H. Zhao, Z. Chen, G. Zheng, C. Wang, and W. Cao, "Characterization of high-field properties of 0.28PIN-0.42PMN-0.30PT single crystal/epoxy 1-3 composite for acoustic transducer applications," Appl. Acoust., vol. 214, Art. no. 109704, 2023, doi: 10.1016/j.apacoust.2023.109704.
[13] R. Guo, S. Li, D. An, T. Han, J. Chen, and W. Cao, "Comprehensive analysis of Mn:PIN-PMN-PT single crystals for Class IV flextensional transducer," Ceram. Int., vol. 44, no. 3, pp. 2864-2868, 2018, doi: 10.1016/j.ceramint.2017.11.033.
[14] J. Zheng, S. Li, and B. Wang, "Design and analysis of a broadband class VII flextensional transducer with the third-generation crystal, Mn:PIN-PMN-PT," Sens. Actuators A Phys., vol. 345, Art. no. 113777, 2022, doi: 10.1016/j.sna.2022.113777.
[15] B. Kwon, S. Pyo, J. Eo, H. S. Seo, and Y. Roh, "Temperature dependence of the full material constants of [011]-poled Mn-doped 0.32PIN-0.39PMN-0.29PT single crystals, and its effect on the performance of an underwater Tonpilz transducer," Sens. Actuators A Phys., vol. 390, Art. no. 116602, 2025, doi: 10.1016/j.sna.2025.116602.
[16] N. Jia, T. Wang, L. Ning, Z. Ma, Y. Dang, C. C. Li, et al., "Conformally Large-Area Single-Crystal Piezocomposites with High Performance for Acoustic Transducers," ACS Appl. Mater. Interfaces, vol. 15, no. 30, pp. 36611-36619, 2023, doi: 10.1021/acsami.3c07673.
[17] W. Hong-wei and W. Li-kun, "Wide band underwater acoustic transducer for stacked 2-2 piezoelectric composite material tube," Ferroelectrics, vol. 520, no. 1, pp. 10-21, 2017, doi: 10.1080/00150193.2017.1328727.
[18] Q. Shi, Z. He, H. Xu, C. Lin, and S. Zhang, "Research on low-frequency bender disk transducer driven by multiple relaxor ferroelectric single crystal disks," Appl. Acoust., vol. 216, Art. no. 109808, 2024, doi: 10.1016/j.apacoust.2023.109808.
[19] S. Wu, Y. Xie, F. Bai, and D. Teng, "Optimal design and experimental study on a novel relaxor ferroelectric single crystal transducer based on face shear vibration mode," Ultrasonics, vol. 156, Art. no. 107763, 2025, doi: 10.1016/j.ultras.2025.107763.
[20] Y. Lei, Z. Gao, G. Gan, W. Bai, Y. Wei, B. Wang, et al., "A High‐Sensitivity, Broadband (1A,1B)‐3 Single‐Crystal Composite Ultrasonic Transducer," Adv. Funct. Mater., vol. 35, no. 11, Art. no. 2417084, 2025, doi: 10.1002/adfm.202417084.
[21] Y. Lei, X. Li, Z. Hou, B. Wang, S. Zheng, Y. Wei, et al., "Dual-Piezo-Charge Strategy in (1-0)-3 Single-Crystal Composite for Enhancing Underwater Acoustic Sensing," Nano-Micro Lett., vol. 18, no. 1, Art. no. 259, 2026, doi: 10.1007/s40820-026-02102-1.
[22] S. Gao, J. Zhou, X. Gao, R. Liu, H. Jiang, J. Chang, et al., "Self‐Powered Underwater Acoustic Beacon System Enabled by Dual Bluff Body Energy Harvester with Relaxor Ferroelectric Crystals," Adv. Mater. Technol., vol. 10, no. 22, Art. no. e00982, 2025, doi: 10.1002/admt.202500982.
[23] Y. Jia, H. Shi, J. Zhang, L. Zang, Z. Mao, and S. Zhang, "Broadband Electrical Matching Network for PZN-PT Single Crystal Underwater Acoustic Transducer," IEEE Sens. J., vol. 26, no. 5, pp. 6614-6624, 2026, doi: 10.1109/jsen.2026.3650828.
[24] K. Echizenya, K. Nakamura, and K. Mizuno, "PMN-PT and PIN-PMN-PT single crystals grown by continuous-feeding Bridgman method," J. Cryst. Growth, vol. 531, Art. no. 125364, 2020, doi: 10.1016/j.jcrysgro.2019.125364.
[25] K. Echizenya, N. Noda, and H. Noro, "Characterization of Mn-Doped PIN-PMN-PT Single Crystal Grown by Continuous-Feeding Bridgman Method," Crystals, vol. 12, no. 9, Art. no. 1183, 2022, doi: 10.3390/cryst12091183.
[26] Z. Chen, T. Deng, R. Chen, D. Lin, W. Di, H. Chen, et al., "Bridgman growth and electrical properties of Nd-doped PMN-PT single crystal with ultrahigh piezoelectricity," CrystEngComm, vol. 24, no. 4, pp. 837-845, 2022, doi: 10.1039/d1ce01116b.
[27] Y. Zhou, Q. Li, F. Zhuo, C. Xu, Q. Yan, Y. Zhang, et al., "Domain switching and polarization fatigue in rhombohedral PIN‐PMN‐PT and Mn‐doped PIN‐PMN‐PT single crystals," J. Am. Ceram. Soc., vol. 102, no. 11, pp. 6668-6679, 2019, doi: 10.1111/jace.16461.
[28] Y. Liu, J. Xia, P. Finkel, S. D. Moss, X. Liao, and J. M. Cairney, "Real-time observation of stress-induced domain evolution in a [011] PIN-PMN-PT relaxor ferroelectric single crystal," Acta Mater., vol. 175, pp. 436-444, 2019, doi: 10.1016/j.actamat.2019.06.023.
[29] L. Cui, Z. Chen, Y. Lü, and W. Cao, "Dependence of coercive field of PIN-PMN-PT single crystal on temperature and frequency," J. Appl. Phys., vol. 131, no. 12, Art. no. 124102, 2022, doi: 10.1063/5.0079332.
[30] P. Finkel, C. Lynch, and A. Amin, "Transduction modality near instability in domain engineered relaxor ferroelectric single crystals," Smart Mater. Struct., vol. 33, no. 1, Art. no. 013001, 2024, doi: 10.1088/1361-665x/ad06de.